How to Use the Periodic Table for Electron Configurations
This video provides a clear, visual method for using the periodic table to determine the electron configuration of any neutral atom. By understanding the structure of the table, you can bypass memorizing complex filling orders. For a more detailed breakdown of this approach, see our guide on Orbital Diagrams & Electron Configuration: Step-by-Step Guide.
Key Concepts
- Periods (Rows): The horizontal rows represent the principal energy level (n).
- Blocks (s, p, d, f): The table is divided into four main blocks based on the highest energy sublevel being filled.
Step 1: Setting Up Your Periodic Table
To use this method, you'll first need to organize your periodic table conceptually. This method connects perfectly with the Comprehensive Overview of Periodic Table and Key Concepts in Chemistry.
- Number the Periods: Label the rows from 1 to 7.
- Identify the Blocks:
- s-block: Groups 1 & 2 (including Helium). Width: 2 elements. Fills the 's' sublevel.
- p-block: Groups 13-18. Width: 6 elements. Fills the 'p' sublevel.
- d-block: Transition metals. Width: 10 elements. Fills the 'd' sublevel.
- f-block: Lanthanides and Actinides. Width: 14 elements. Fills the 'f' sublevel.
The width of each block perfectly matches the maximum number of electrons that sublevel can hold (s=2, p=6, d=10, f=14). For example, the 'd' block has 5 orbitals holding 2 electrons each for a total of 10. These patterns are core to Electron Configuration Patterns: Quantum Numbers & Orbital Rules Explained.
Step 2: The Numbering Trick for 'd' and 'f' Blocks
When filling configurations, the energy level for the 'd' block is one less than the period number. The 'f' block level is two less. This is crucial for accuracy. This concept is fundamental to Orbital Diagrams and Electron Configuration: Aufbau, Pauli, and Hund's Rules Explained.
- d-block: Period 4 is 3d, Period 5 is 4d, Period 6 is 5d, Period 7 is 6d.
- f-block: Period 6 is 4f, Period 7 is 5f.
Step 3: Writing the Configuration – The Grid Method
The process is simple: start at Hydrogen, move left-to-right through each row, and write the configuration as you go.
General Rule: You write [Period Number][Block Letter][Number of Elements Passed].
Example 1: Carbon (C) – (Atomic Number 6)
- Start at Hydrogen: Go through row 1.
- Period 1, s-block, pass 2 elements:
1s2
- Period 1, s-block, pass 2 elements:
- Move to Row 2: Start with the s-block.
- Period 2, s-block, pass 2 elements (Li, Be):
2s2
- Period 2, s-block, pass 2 elements (Li, Be):
- Continue in Row 2: Move to the p-block.
- Period 2, p-block, pass 2 elements (B, C):
2p2
- Period 2, p-block, pass 2 elements (B, C):
Final Configuration: 1s2 2s2 2p2
Example 2: Cobalt (Co) – (Atomic Number 27)
- Row 1:
1s2 - Row 2:
2s2 2p6 - Row 3:
3s2 3p6 - Row 4, s-block:
4s2(Period 4) - Row 4, d-block:
3d7(Period 4 minus 1)
Final Configuration: 1s2 2s2 2p6 3s2 3p6 4s2 3d7
Example 3: Lead (Pb) – (Atomic Number 82)
- Configuration:
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p2
Note: The 'f' block (4f and 5f) is found after the 's' block but before the 'd' block in Periods 6 & 7. The method logically passes through these elements in order. For further practice with this technique, you can review our Easy Method to Write Electron Configurations Using Orbital Diagrams.
Why This Works
The organization of the periodic table is a direct reflection of quantum mechanics. The block widths and period numbers form a
hello everyone and welcome back my name is mr covald and in this video i'm going to show you how you can use the periodic
table to find the electron affinity of any
atom on the periodic table okay so let's get into this but before we get into this
remember to subscribe to my channel hit that notification bell on the top so you can be notified other videos i put
down please put comments in the comment section let me know what you think and
if you have any questions that i can answer please hit that like button
now let's get into this so so we have our periodic table we're
going to set this up so that way we can figure out what the electron configurations are
so the first thing we need to do is we're going to number the sides here so
on your periodic table along the left hand side
you will see that the rows are numbered and we call these rows periods so in the periodic table we call them periods so
each period or row has a number so we're going to number from 1
to 7 on the bottom so let's go ahead and do that so if you have your own periodic table
you can number this as well yours maybe look a little bit different than mine but that's okay
so we're gonna put a one a two a three
a four a five six and seven okay so we've got those
periods numbered we got the rows numbered so next
we have to block out certain things or certain parts of our periodic table so that we
can recognize them as different parts you can kind of see that they're different
uh right away but we're going to kind of highlight uh the different parts of the periodic table
so let's get some different colors here okay so this first part here
uh we're gonna look at this part here you can see that this part is kind of by itself
so we're going to color that red now the thing i want to point out is that for the purposes of
electron configuration we'll notice that helium is over here but we're going to move it over here for
the purposes of electron configuration we're going to put it in this group here the reason for that is because helium
kind of behaves as far as electron configurations go it goes over here mainly because
that first energy level that's filled up only has a 1s2 if you remember from electron configurations
so the 1s sublevel can only fill two electrons in that sublevel
and so that goes to helium helium kind of fits
there in this group here so i'm kind of jumping ahead of myself so let's let's kind of
put this over here so we're going to kind of cross this out a little bit
so we're going to and we're going to move that over here so we got
h e okay so
let us kind of cro color this a little bit or our outline
we're going to outline this with red you could pick your own color it doesn't have to be red i'm just using
red because that's available but you can use whatever color you want all right so that's kind of separated
we're gonna uh now separate the next one or like highlight the next one and the next one
we're gonna look at is this block here so this block here seems to be one by itself or
it seems to stick out a little bit so we're going to highlight that a little bit more
so we're going to put we're gonna use blue or i'm gonna use blue you can use
whatever color you want okay and the next one
this part here seems to be a different part
so we're going to highlight this okay
and then finally we're going to highlight
this part here we're going to use orange so i'm going to use orange here again you can use
whatever color you want you can make it all pretty mine's not that pretty
okay so here we go so now i want to point something out to you so this is going to be mind-blowing
it was mind-blowing to me so if you've never seen this before get ready to
have your world rocked so we've learned that in electronic
figurations you have the s sublevel and so you think okay so think about how many orbitals are in that
that sublevel we only ever have one s orbital every s sublevel has only one s orbital
and how many electrons can fit into that 1s orbital 2 maximum right
so if we look here how many elements wide is this part here if we were to count
how many elements wide is that two okay
so far so good now now let's think about the p sublevel the p sublevel
has how many p orbitals it has
three right you have the p x the p y and the p z orbitals that are oriented in space differently along the axes
and each of those can hold how many electrons each two so each
p orbital holds two electrons you have three p orbitals that's a total of six electrons
and how many elements wide is this block if you count how many do you count
one two three four five six it's six wide interesting
interesting what about the d sub level right you have the d sub level how many d orbitals
do you have at the d sub level anyone bueller
bueller we have five d orbitals so five d orbitals
each d orbital holds two electrons max and that means you have a total of
ten electrons in the d orbital and if i was to ask you
to count the width of this block right here how many elements wide would that be
let's see one two three four five six seven eight nine ten wow
and finally we have this block here so remember we have the f sub level f sub level
can has seven seven orbitals each orbital holds two electrons i think you know where i'm
going with this yes that's right seven orbitals two electrons each 14
electrons i think you can guess the width of this block here 1 2 3 4 5 6 7 8 9 10 11 12 13 14. amazing
amazing um that is amazing because this table
uh was originally i mean when it was set up it wasn't exactly set up this way but i
mean it was pretty much set up this way before we knew anything about
protons electrons neutrons right and so the periodic table when it was
organized uh eventually in like 1914 it was organized by mosley to according to
atomic number but before that it was organized by atomic mass but atomic number atomic mass doesn't
really change as a couple it's like maybe uh maybe four elements switch places
based on they differ based on mass versus atomic number but it's pretty much this
way so now we have quantum theory we have
orbitals we have orbital diagrams we have energy levels and you can see that the different sub levels match perfectly
with the periodic table that is amazing i don't know about you but that just blows my mind
so what we're going to do now is we are going to label the blocks so since since the s sublevel
has two electrons max and this is too wide we're going to call that or they call that i i didn't come up with this
this is called the s block okay
next since we have this block here is six wide and the p
sub level ten is is uh has a maximum of six electrons we're going to call this
p block next here since the d sublevel has 10
electrons max and this is 10 elements wide this is called
the d block and finally since this part here
matches with the f sublevel because the f sub level holds a maximum of 14 electrons this has 14 elements across
this is going to be the f block the f block
okay so now we have our periodic table set up and we broken up into s p d and f block
and we have our periods numbered now
the thing to remember is these periods uh match up
with the energy level that you are at one a couple things i want to add so
the other thing you want to add here is i'm going to use orange again
so we have to number these differently here these rows are going to be numbered
differently and these two rows are going to be numbered slightly differently um
so for when we're getting into the d block we're going to have a 3 here so instead
of a 4 this is going to be 3 and these are going to differ by minus 1. so 5
minus one is four six minus one is five seven minus one is six
okay and then for these two
uh these guys get inserted into here
right after barium or i should say lanthium and actium so you'll see 58 you get 57
58 and then this is 89 90 for thorium so these two rows
actually get inserted here and so when we do that when we're going from six to
when we're doing f the these are going to be labeled these are going to be numbered i should
say 2 less than the row or period you're in so this is
6. so this row here is going to have
a four so that's going to be four and then this row here is going to be in
the seven row but when we get here that's going to be a five so it's two less than the row
that you're in okay so we have our table set up
so now you can use your periodic table to write electron configurations
how does that work well let me show you i'm going to move this over
and we're going to do a couple of examples
okay i'm gonna use a piece of paper and pen pen so that
you can see it more easily i'm gonna zoom in a little bit so we can see the periodic table
maybe that's yeah there we go okay so
that's good enough for now all right so here's my piece of paper
all right let's see how this is done so the way you use the periodic table to write your electron configurations is is
this you first need to know what element you have and how many electrons that element
has we're assuming neutral so if you're given an element and you want to know how many electrons it has if
it's a neutral element neutral atom then the electrons are going to be equal to the protons and the protons are given to
you by the atomic number so remember the atomic number is this top number up here so the atomic number of nickel is 28 the
atomic number of of arsenic is 33 and so on so
if you know the number of electrons then all you need to do remember the number of electrons are being added to
your orbital diagram you start from the lowest energy level to moving up to the highest going
through the different sub-levels and the sub-levels differ in energy as well right so the s orbital is lower in
energy than the p the p is lower than the d and the d is lower than the f so you're going to fill in the s and then
the p and then the d and the f and things like that so
so the periodic table actually tells you what to do because all you need to do
is start always at number one helium so you just start at
the beginning of your periodic table and you write down the row that you're in because remember the row corresponds
to the energy level the block that you're in the block corresponds to the sub level
and the number of elements that you go through to get through that block and that's going to correspond to the number
of electrons so let's do a quick example um let's do carbon carbon i'll do a simple one here so carbon is here
carbon's number six okay so six electrons so all i'm gonna do is i'm gonna
start it here a hydrogen here and i'm gonna go through each row right each row
until i get to carbon but and i'm going in numerical order you're going in numerical order so
one and then two for helium three four five six right and as i'm going numerically
through the periodic table i'm writing down the row that i go through the block that i go through and how many elements
in that block i go through okay so uh carbon let's do carbon so c for carbon
so i start at hydrogen i got to go through hydrogen i got to start from one and i got to get to six
so as i'm going through the elements i am writing down the row
the block and the number of number of elements so
i start here i have hydrogen and helium i'm going through those because i gotta get to number six so one and two are
done so that's row one so i'm writing out one i'm in the s
block s and i gotta go through two elements so two
now i'm done with that row or i'm here there's nothing else so i got to go numerically to lithium
now i'm in the second row so that's 2. what what block am i in s s
and then i have to go through these two to get to six so i go three four so i go through two of those elements so that's
two now i jump over to the p block number five is next
so i'm now in the p block i'm still in the second period second row so i'm it's going to
be two and then i put p and how many elements do i have to go
through one two so i have to go through two elements so that's a two
for the p so that ladies and gentlemen is the electron configuration for carbon that's it that's how you use the
periodic table okay let's keep going let's do uh let's do a larger one let's do iron
i like iron no let's do cobalt my last name is covalt with the v let's
do cobalt so that's going to be co yes
cobalt is my favorite element okay so it's the same thing so now i have 27 electrons right so number 27
means i have 27 protons i'm going to assume that the atom is neutral so that means i have 27 electrons so i'm going
to go from 1 all the way to 27 and as i'm going
through the periodic table i'm writing down the the period or row that i'm in the
block them in and the number of elements i have to go through because the row
these numbers here and these numbers here and these numbers here right uh represent the energy level
of that sublevel and the block here represents the sub
sublevels that you're in and the number of elements you go through represents the number of
electrons you're putting in into that sublevel okay let's let's get into this so i'm
starting with hydrogen and i'm working my way numerically until i get to cobalt
okay so i go through the first row i'm in first row s block so 1
s i got to go through those two so that's going to be a two
i continue to number three now i'm in the period number two that's going to be the second energy level i'm in the s
block so that's 2s and i'm going through the 2s 3 4 so that's 2.
and i jump over now i'm it's still in the second row second period so that's still a two
so it's going to be now 2p because now i'm in the p block and i have to get to cobalt so i got to
go through all of these one two three four five six all the way to ten so that's going to be six electrons
in the p sublevel second sub level now i'm all the way over at neon so i got to keep
going because i got to get to number 27 i'm only at number 10. so keep going so i go to 11. now i'm at sodium i'm in a
period three so third energy level s block so that's 3 s
i got to go through sodium and magnesium
so that's 2 so that's 3s2 and then i gotta jump over again to aluminum
so now i'm in the uh the p block again i'm still in the third the third row third energy level third
period so that's going to be 3p i gotta go through one two three four five six to get to 18. again my goal is
cobalt as 27 so i got to go through these so that's six elements six electrons
in that sublevel now i'm at argonne now i gotta jump down to number 19 which is potassium in the fourth period so
that's energy level number four s block so that's 4s
and that's 2 1 2. i got to go through 2 to get to 20 24 calcium so 4s2 now i'm jumping to the
d block here so 20 to 21 i'm in the d block notice the number has gone down one so that's 3d
not 4d 3d so 3d and i got to count one two three four five six seven so that's going to be seven
in the 3d sub level and that ladies and gentlemen is the
electron configuration for for the uh element cobalt
okay let's do one more let's do a longer one because i want to kind of discuss something here
last one uh we're gonna do um
let's see we're gonna do let's do uh polonium
p-o or we could do lead let's do lead
let's do lead number 82 we're going to do 82 electrons so lead pb so same thing
um we have 82 electrons so we're gonna start with one hydrogen and work our way through
to get to lead and then that's gonna involve the f block and i'll show you something
there okay so
we're going to start with hydrogen 1s2 so we're going to go through
the 1s we go through the two elements so we're going through these two
elements one two two's there so we're putting helium
there right so one two now we go down to three we're in the second period second energy so 2s
we go through two elements there so that's two electrons added to the 2s
and we jump over again to the p block that's going to be 2p we're in the second period still so
that's energy level 2 p we go through 6 elements we're going to 82 in this one so that's
going to be 6 neon jump down to 11 sodium we're in period three so that's
third energy level s block three s and we're going through two the two elements
jumping across to the p block here still in period three
so we're going to go through these six elements we're in the third three p sub level
so that's three third row third period p block six elements through so that's three
p six okay now we're at argon again we're gonna jump down to 19 for potassium
that's the fourth period so that 4s we're in the s block so for
fourth energy level s sublevel we're gonna go through these two potassium calcium so that's
two now we're in the d block with number twenty one so again three d so we're at
third energy level d sublevel so 3d we're going to go through all 10 of those so that's going to be 10
3d 10. okay we're going to have to give ourselves
some room here so i'm going to go down here so after
the d block we go back to four i forgot to write that down we should uh
we should go back to the four here so when we go back to the p we're going to go back to the original
numbers so 4 5 6
and 7. so here
here we're going to go from okay 3d 10 to 4p again so now we're in the p block
we're back at the fourth level so four p we're right down here so four p and
we're going to go through all six elements so that's six electrons now i'm at krypton i gotta jump down from 36 to
37 rubidium so now i'm in the fifth period which is energy level five and
i'm in the s block so that's 5s so i'm going to 5s i go through those two
so then i'm going to be 5s2 now i'm jump into the d block again so that's 4d and i'm going to go through
all 10 of those elements so that's 4 d 10.
so now i'm at cadmium and now i'm jumping to 49 with it which
is indium and that's going to be back to 5. so that's 5p i'm in the p block again so 5
p i'm going through all six elements to get the xenon so that's 6 electrons in
the 5p sublevel now i'm at xenon and i keep going so because i want to get to 82 i'm not
there yet so 54 jumping down to 55 cesium six
uh sixth period so period number six six uh uh energy level number six so this is 6s i'm in the s block
now so that's 6 s 2 because i got to go through these two and now this is where um we don't really
follow the periodic table exactly and you'll notice here uh that lanthium seems to be
in the d block right lathium and actinium uh but and then we're inserting uh
ce after 58 we're not going to follow exactly how this periodic table is
normally
The video introduces a 'grid method' where you simply move left-to-right across each row (period) of the periodic table, starting at hydrogen. As you pass through each block (s, p, d, f), you record the configuration using the formula [Period Number][Block Letter][Number of Elements Passed]. This bypasses the need to memorize the Aufbau principle order.
For d-block elements, the energy level (principal quantum number) is one less than the period number. For example, elements in period 4 are in the 3d block, period 5 is 4d, and so on. For f-block elements, the energy level is two less than the period number—period 6 corresponds to 4f, and period 7 corresponds to 5f.
The width of each block matches the maximum number of electrons that sublevel can hold: s-block holds 2 electrons (width 2), p-block holds 6 (width 6), d-block holds 10 (width 10), and f-block holds 14 (width 14). These widths correspond to the number of orbitals (1, 3, 5, and 7, respectively) times 2 electrons each.
Start at hydrogen and move through period 1: you pass 2 elements in the s-block, so write 1s². Then move to period 2: pass 2 elements (Li, Be) in the s-block for 2s², then move to the p-block and pass 2 elements (B, C) for 2p². The final configuration is 1s² 2s² 2p².
The periodic table's layout naturally accounts for this order. After passing through the 6s block (period 6), you encounter the f-block (4f) and then the d-block (5d) before reaching the p-block (6p). The method follows the table's left-to-right, top-to-bottom flow, which reflects the actual filling order dictated by quantum mechanics.
Yes, the method works for all neutral atoms. Simply start at hydrogen and traverse every row in order. For transition metals (d-block), remember to subtract 1 from the period number for the energy level. For f-block elements, subtract 2. The table's structure inherently guides you through the correct sequence of subshells.
The periodic table is structured based on quantum numbers and orbital filling rules. The period number indicates the principal energy level (n), while the block letters (s, p, d, f) correspond to the azimuthal quantum number (l). The block widths match the maximum electron capacity of each sublevel, making the table a visual representation of the Aufbau principle, Pauli exclusion principle, and Hund's rule.
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