How We Know What Elements Are in Stars
Astronomers identify elements in stars by analyzing the wavelengths of light that are absorbed or emitted. Each element produces a unique spectral pattern, like a fingerprint, because the energy levels within its atoms differ from every other element. To understand how stars formed in the first place and where these elements came from, you can explore the Big Bang Theory: How All Elements Were Created From the Beginning.
The Atomic Process: Absorption & Emission
Ground State vs. Excited State
- Ground state: Electron at lowest energy level (closest to nucleus)
- Excited state: Electron absorbs energy and jumps to a higher energy level (farther from nucleus)
Key Steps:
- Energy absorption: An electron in an atom absorbs energy (e.g., heat from a star)
- Electron jumps: Moves from ground state to an excited state (higher energy level)
- Relaxation: The electron quickly falls back to a lower energy level
- Photon emission: When the electron falls, it releases the extra energy as a photon of light
The energy of the emitted photon equals the energy difference between the two levels: E = h × f (where h = Planck's constant, f = frequency).
The Connection Between Energy and Wavelength
- High energy → Short wavelength (e.g., violet light)
- Low energy → Long wavelength (e.g., red light)
Color Order (ROY G BIV):
- Red (lowest energy, longest wavelength)
- Orange
- Yellow
- Green
- Blue
- Indigo
- Violet (highest energy, shortest wavelength)
The Electron Transitions & Spectral Series
- Lyman Series: Transitions to n=1 (ultraviolet, invisible to human eye)
- Balmer Series: Transitions to n=2 (visible light)
- Paschen Series: Transitions to n=3 (infrared, invisible)
Larger electron jumps produce higher energy (shorter wavelength) photons. Smaller jumps produce lower energy (longer wavelength) photons.
Why Each Element Has a Unique Spectrum
- Different elements have different numbers of electrons
- Additional electrons cause the atom's energy levels to shift slightly
- Result: Every element has a unique set of possible energy transitions, creating a unique spectral fingerprint
If you need a refresher on the fundamentals of matter, see Atoms and Elements: Basic Building Blocks of Matter Explained.
Two Types of Spectra
1. Emission Spectrum
- Setup: Hot gas emits light → Light passes through a prism → Color bands appear
- How it works: Electrons in hot gas absorb energy, jump up, then fall back down, emitting specific wavelengths of light
- What you see: Bright colored lines on a dark background
2. Absorption Spectrum
- Setup: Light source (producing all wavelengths) → Passes through cool gas → Goes through prism
- How it works: The cool gas absorbs specific wavelengths (the same ones it would emit if hot)
- What you see: A continuous rainbow with dark bands where light was absorbed
For stars, we typically observe absorption spectra. The star's hot interior produces all wavelengths, but the cooler outer layers absorb specific wavelengths.
Real-World Applications
Flame Tests (Lab Demonstration)
- Lithium chloride: Reddish color
- Sodium chloride: Bright yellow color → Indicates sodium (Na)
- Potassium chloride: Magenta/purple color
- Rubidium chloride: Varies
- Calcium chloride: Bright orange → Indicates calcium (Ca)
Fireworks
- Blue: Copper compounds (e.g., copper chloride)
- Yellow: Sodium compounds
- Orange: Calcium compounds
- Mixing different elements creates multicolored fireworks displays
Analyzing Starlight
Astronomers capture the light from stars and spread it through a spectroscope (prism-like device). By comparing the observed spectral lines (emission or absorption bands) to known elemental fingerprints measured in laboratories on Earth, they can identify which elements are present in distant stars. The instrument used for this is explained in detail in How a Spectrophotometer Works: Light, Diffraction, and Sample Analysis.
Example Stars:
- Betelgeuse: Shows specific absorption bands indicating certain elements
- Rigel: Has its own unique absorption spectrum
Summary
- Elements absorb or emit specific wavelengths of light based on their unique electron energy levels
- These wavelengths form a spectral fingerprint unique to each element
- Emission spectra show bright lines; absorption spectra show dark bands on a rainbow background
- By matching observed spectral lines with laboratory samples, astronomers determine what stars are made of
This method works because the atoms of each element have a unique set of energy level gaps, so no two elements produce identical spectral patterns. For a deeper dive into how these building blocks are classified in chemistry, read Understanding the Classification of Elements and Periodic Properties in Chemistry.
hello everyone and welcome back my name is Mr kovalt and in this video we're going to talk about how we know what
elements are in in the stars and in order to talk about that we're needing we're going to need to talk about the
emission and absorption spectra of different elements so let's get into this
so how do we know which stars have which elements well we can analyze the wavelengths of
light that are absorbed or released by The Stars themselves and so what this means is that depending
on what elements are in a particular star different wavelengths of light are absorbed or released from the stars
and so if we can detect that and see which bands of light or which wavelengths of light are absorbed or
released by The Stars we can then indicate what elements must be in there to to uh
uh to give us that result okay so before we get into that we need to
talk about what's happening in the atom right what's happening in the atom when uh when you get this absorption or
release of energy and so uh we what we need to focus on are the electrons so when you put energy into the atoms of a
substance uh it's the electrons that are going to pick up some of that energy and so if you give the atom energy the
electrons can absorb that energy and then they're then they go up to a higher energy level so if you remember from a
previous video we talked about how the energy of the electron is associated with the energy levels that it's at and
so the uh the the electrons tend to be at lower Energies and they're going to be closer to the
nucleus so they're going to be down lower right but if they absorb some energy
then that's going to kick them up to a higher energy level they're going to then be farther away from the nucleus so
uh in the beginning we can see that this electron here is in its the lowest energy State possible so we call that
the ground state and so when we put the energy into the electron when the electron absorbs
energy it then jumps up to a higher energy level and we call that the excited state so think about an analogy
is like when you get excited that means that you have energy okay so the electron absorbs energy jumps up to a
higher energy State called the excited state ground state to excited state so this is very much like you climbing a
ladder right so again when you're closer to the ground you have a lower gravitational potential energy but as
you climb up to higher rungs on the ladder your gravitational potential energy increases same thing for the
electron so here we have a kind of potential energy for the electron in its ground state this is the lowest energy
when it absorbs energy it goes up to a higher energy State more potential energy
but electrons are not going to stay in that position very long right so again they don't want to be in a higher energy
State they they actually prefer to be in a lower energy state so what's going to happen is the electron is going to then
release that energy that it absorbed and go back down to the lower energy state it was so it's going to relax we say
this is relaxing so the excited electron relaxes back down to ground state in doing so it loses that energy so going
from a high energy to low energy it's got to lose that energy and it loses that energy often in the form of light
and so again it's following the alpha principle right the alpha principle says electrons want to be in the lower or
lowest energy possible so they're going to fall back down so again person on the ladder they might slip and fall and that
and as they fall they're going back down towards the ground losing gravitational potential energy so this is analogous
and so here you can see in this picture you've got energy level two and energy level one so the electron here went from
ground state here E1 is its ground state and it goes up to E2 higher energy level because it absorbed energy
and then it comes back down and when it does it releases a photon of light so remember particles of light we call
those photons and they have wavelengths and the the energy of the light we can figure that out by multiplying this
planks constant times the frequency of the light uh which is the inverse of the
wavelength and so here's the equation down here but the thing to keep in mind here is that the energy difference here
between the two energy levels is the same as the energy and the light that's being released so if you want to know
what energy levels or how big of a gap here you then measure the energy of the light and you'll know how much of a gap
between the energy levels the electron trans transition to through and so there's different ways to draw
this same picture so basically you want to make sure that you're showing If energy is coming in or out in which
direction the electron is moving right so here and you've got the Bohr model here and you've got two orbits and so in
this picture you have the electron moving from an inner orbit that is closer to the nucleus so this is low
energy because remember the closer you are to the nucleus the lower your potential energy so it's like being
close to the Earth right closer you are to the Earth the lower your gravitational potential energy but if
you uh go to a higher energy level this higher orbit which is farther from the nucleus so that indicates higher energy
so this electron here absorbs energy so there's the energy going in the electron jumps up to a higher energy state so it
gets excited and there it is at a higher energy State because it absorbed energy and then later on very soon afterwards
the electron is going to relax back down to the lower energy State and when it loses that energy it releases that
energy in the form of light so the light then has a certain amount of energy that energy of the light is equal to the Gap
that the electron moved between and so that's going to indicate a certain wavelength because wavelength
and and energy is really are related to each other and again we can use this picture here
for the same idea here we have a lower energy State here we have a higher energy State you can heat up the atoms
putting energy into the atoms and so the electrons will pick up some of that energy so they absorb the energy going
to a higher energy state which is now the excited state and then they relax back down to the lower energy State at
releasing light and again that light the energy of the light is going to have the same amount of energy that is the
difference between the two energy states and so that energy is going to be related to wavelength
okay so we can then you know um see the light that's emitted from these different substances so the amount
of energy that is given off by these substances uh well is going to depend on the energy levels that the electron is
falling from we just saw that so the the energy level how big of a gap there is it means that the
um the difference in energy is going to be larger and if the electron jumps from uh jumps a larger distance from a high
energy to low energy then the amount of then the light the photon of light emitted is going to have more energy and
therefore it's going to have a a a certain wavelength and so here we can see in this picture that the amount of
energy so we have high energy down here and we have low energy up here and you could see the wavelength changing so
high energy is associated with very short wavelengths and low energy is associated with longer
wavelengths so as we were talking about before the the larger the gap between the energy
levels that the electron is jumping between right so if the electron Falls from one energy level to a lower energy
level if that is a larger Gap that means the photon that's released is going to have more energy and if it has more
energy than the wavelength is going to be smaller if the Gap is smaller if the Gap that the electron is falling between
is smaller then that means the photon light Photon that's being released is going to have smaller energy and
therefore longer wavelength and so here in the middle you could see this visible
spectrum this is the spectrum of light that we can actually see anything beyond that Spectrum we can't see so UV light
uh pet scans gamma rays we can't see those those are invisible to us and even on this side when they're longer these
are invisible because our eyes can only pick up wavelengths within this small band here and the thing I want to point
out here is that you could see here that the color of light is in a certain order so red is on top Violet is on the bottom
and we'll talk about that in a moment so here we have different series of light and so the electron
can jump from any level to any level right so here we have this small inner one that would be your n equals one that
really tiny circle around the nucleus right so that's energy level number one and then this second one here is energy
level number two this third one here is energy level number three energy level number four energy level
number five and then we have six out here and seven so we have seven energy levels being represented here and the
electron can jump up to any one of these levels and fall back down to a lower level
so the electron can jump to this level fall back down to this level or it could jump up to this level fall back down to
this level so you could see that there's different uh ways in which the electron can go down to a lower level and as I
was saying before the larger the jump down by the electron the more energy that's
released right because you got a larger gap between the energy levels larger Gap means you know larger difference in
energy and so that means if the electron jumps from way up here down to here the energy is going to be is that's released
is more and so the photon of light that's released is going to have higher energy and therefore lower wavelength
you if you see down here the electron jumps from this energy level down to this energy level so it's got a smaller
Gap so the light that's released from that electron when it moves down to this lower energy level is going to be
smaller so small energy means longer wavelengths and so remember the wavelength of light is associated with a
particular color right so here in this series called the Balmer Series this is where we can see a visible light now
these other series The Lyman series and the pascan Series bracket series and so on
these series also produce light but a lot of the light that we see
is is not visible to us so much and much of the Rays much of the light that's being
released by these transitions are not visible to us but this series is visible to us
and so what happens when these electrons uh release the light well different elements have different
numbers of electrons and those electrons are filling in different energy levels and the thing we have to understand is
that as we put more electrons into a particular atom right of a particular element right
every time you put an electron into an atom into a different energy levels those that additional electron causes
the energy levels to change a little bit so no element no atom of a particular element is going to have the exact same
energy levels as another atom of a different element because different elements have different electrons and
the number of electrons kind causes the energy levels to change a little bit so when you look at what energy is being
absorbed or emitted by a particular element only that element will produce those
different waves of light those different wavelengths of light so this is like a fingerprint of an element so just like
we have fingerprints to identify different humans and every human has a different fingerprint so also the
elements have different emission spectrums they have different Atomic Spectra that identify that element and
only that element so hydrogen you could see these bands of Light by High hydrogen only hydrogen will give those
bands of light so these like the these are the bands of light or wavelengths of light that is emitted by hydrogen and
hydrogen alone so here we have all these bands of light from neon you can see that there's only a few bands of light
from hydrogen hydrogen only has one electron so there's not as many transitions by the electron from one
energy level to the other but neon has more electrons so there's many more transitions done by those electrons and
iron still has more bands of light because it has more electrons but none of these bands of light and iron are
going to be superimposed or match up with any of these bands in neon because the energy levels are different they're
they can be very close but they're going to be slightly different okay so the energy Spectrum so you can
measure the exact wavelength and when we get the light so we're going to get the light from the atoms we can then measure
the exact wavelength of the light and then that wavelength will tell us how big of an energy gap that electron fell
from right so we know that as the electron Falls from lower to from higher to lower it releases a a photon of light
with a wavelength and that wavelength is associated with the amount of energy lost by the electron which is associated
with how big that Gap is and so here we can see the rainbow of light
and as I was telling you before the order of the colors tells you the uh the uh energy so red has low energy purple
has high energy or indigo violet if you want to go that right way so low energy is associated with longer wavelengths
and high energy associated with shorter wavelengths so as you go from red to purple you are going from low to high
energy so purple light has higher energy than red light so that what that means is that when you put if you find a
purple light being emitted from an atom that means that the electron that that gave off that light was
uh relaxing or going through uh through a different Gap a larger Gap in its energy so it fell down a larger Gap and
produced a higher energy light so it lost more energy and produced uh that light if you see red light then the
electron only lost a little bit of energy because it jumped down to a lower energy that was not as big of a gap
between them and so you can see that with orange yellow green and blue so the easy way to remember the order of the
colors is by remembering Roy G Biv that's think of that as someone's name Roy is the first name g is the middle
initial and Biv is the last name so Roy red orange yellow G for green and then Biv is blue indigo violet here here they
have purple but indigo violet is often said as well so how do we get these uh emission
Spectra so there's two ways that you can get uh Spectra so uh wavelengths
um what wavelengths does it give off or which wavelengths does it absorb so either way is used so when we're looking
at emission Spectra the way this works is we're looking at a hot gas we're looking at the light that is absorbed or
given off by that hot gas so the light that's given off passes through a prism and then as the light passes through a
prism different wavelengths of light are separated from each other based upon how quickly they can go through this this
prism and different wavelengths of light can go uh more or less quickly through there and so you get the bending of the
light and they get separated here and so this is an example of emission spectrum so different light bands that are
produced get passed through this prism and then they get separated here so these are the emission this would be an
emission spectrum of whatever this hot gas is another way you can do it is through an absorption spectrum and the
way this is the opposite the way this works is you have a light source again and so this light source is producing
all of the wavelengths of light so all the wave all the different wavelengths of light are passing through this cold
gas now we have a cold gas this cold gas is now going to absorb certain wavelengths of light instead of emitting
them so most of the light is going to pass through this cold gas except for the ones that are absorbed by the gas
and so the light then passes through the prism and then you get this more color this this uh the spectrum of color and
what's going to be different here is that instead of having the bands of light show up you're going to have dark
spots show up where the bands of light should be and they don't show up because that light was absorbed by the gas
so either way we can identify what the element is either by what what
wavelengths were absorbed or what wavelengths were emitted and they are going to be the same wavelengths it's
just that one is showing you them as emitted and one is showing you them as absorbed
and so here's the example again so here's what you would see from natural light or from a light bulb so you have a
light bulb giving off all the wavelengths of light those wavelengths of light pass through the prism and you
get this rainbow this continuous Spectrum there's no gaps it's all rainbow all together that would be
normal the emission spectrum as I said you have the hot gas and the hot gas is emitting certain wavelengths of light
those certain wavelengths of light are passed through a prism and then they are separated and you can see the bands of
light show up here on the Spectrum you'll notice that most of it is dark because this hot gas is not emitting all
of the wavelengths of light it's only emitting a few and so only the light that is emitted is being shown up and so
this will be identified this will help identify what the element is so this is what happens when we do a lab
now here when we're looking at the sun here when we get an emission spectrum the light source that's emitting all the
wavelengths of light passes through a cold gas some of those wavelengths of light are going to be absorbed so the
same wavelengths of light that were emitted here are now going to be absorbed here and so the rest of the
light that passes through goes through the prism and then you can see that they are you can see the colors of light here
and then the ones that are missing are the exact ones that are emitted here but they're emit they're missing here
because the cold gas absorbed them so this is an absorption spectrum and this is what happens in the Stars right we so
normally we have absorption Spectrum so what about flame tests so we can do flame tests in a lab and we can say oh
from the flame test we can identify the different colors and different colors will identify uh different elements in
the substance and so here you can see that you got lithium chloride sodium chloride potassium chloride rubidium
chloride they're all chlorides but they're producing different colors so if it was the chloride that was producing
the color they should be all the same color but they don't have the same color so it must be the metal
ion here the first ion lithium sodium potassium those are the ions that are producing the color so here you can see
lithium producing reddish color here sodium is producing a bright yellow color
potassium sort of you know magenta color if you will calcium down here is producing a really bright orange color
and so on so you can identify what element there is by the color that you see because again different elements
produce different wavelengths of light and therefore different colors and so this is where your fireworks come in
different fireworks produce different colors because they have different elements mixed in with the uh the
firework itself so you if you see blue that means copper chloride was put in there or maybe it was copper some other
copper compound copper is a typical color that uh that a typical element that gives blue if you have sodium in
there then you would see a yellow color so yellow is indicative of sodium being in the firework calcium chloride we saw
calcium given orange color so if you see orange in your firework then that indicates that calcium was in in there
so this is why different fireworks give you different colors and you can get a mixture of colors because you have a
mixture of different elements in the fireworks and once again we can see here that we
have these different emission Spectra and these are the Fingerprints of different elements so just like we
humans have different fingerprints and we can be identified by our fingerprints each element has a different Spectrum
with different bands of light different wavelengths of light that show up and these Spectra will identify the element
coming from a particular Sun so we can identify what elements are in different Stars by analyzing the different
wavelengths that come in and if those wavelengths come line up with particular elements then we know that in that
particular sun or Star we have those elements and here again is an example of a
absorption Spectrum so same thing you can see here that you have a rainbow but instead of seeing bands of light you see
dark bands you see uh bands that have no light and that's because they were absorbed by the element and so in this
case we're looking for dark spots and if those dark spots line up where light should be for that particular element
then we identify that element as being hydrogen or helium you know depending on where we see those dark bands so again
here this is where the absorption is Korean and so we don't see the light because it's been absorbed by the
element in that star or sun and again here's the different uh bands of light this is different Spectra that
we see from different um stars here's the Spectrum from the Beetlejuice yes there is a star called
Beetlejuice and so you can see the bands of light uh and you can see the dark bands where there is no light so you can
identify what elements are in that star here rigel this is the another uh absorption Spectrum for that star and so
we can use these to identify what what elements are there and so that's it for this video I hope
you enjoyed this video I hope this was educational if you like this video please hit that like button share this
video subscribe to my channel hit that notification Bell let me know what you think in this in the comments ask
questions I love questions thanks for joining me have a great day
Astronomers use spectroscopy to analyze the light from stars. The starlight is passed through a spectroscope, which splits it into a spectrum. By comparing the observed absorption or emission lines (the spectral fingerprint) with known elemental patterns measured in labs on Earth, they can determine which elements are present in the star.
An emission spectrum is created when hot gas emits light at specific wavelengths, appearing as bright colored lines on a dark background. In contrast, an absorption spectrum occurs when light passes through a cooler gas, which absorbs certain wavelengths, producing a continuous rainbow spectrum crossed by dark bands. For stars, we typically observe an absorption spectrum because the hot interior emits all wavelengths, but the cooler outer layers absorb specific ones.
Each element has a unique number of electrons, which causes the energy levels within its atoms to be arranged differently. This means each element has a distinct set of possible energy transitions for its electrons. Since the wavelength (or color) of light emitted or absorbed depends on the energy difference between these levels, every element produces a unique pattern of spectral lines—like a fingerprint.
When an electron absorbs energy, it jumps from its ground state (lowest energy level) to an excited state (higher energy level). As it falls back down, it releases the extra energy as a photon of light. The energy of the emitted photon equals the energy difference between the two levels (E = h × f), which determines its wavelength: higher energy transitions produce shorter wavelengths (e.g., violet), while lower energy transitions produce longer wavelengths (e.g., red).
These series describe the spectral lines resulting from electron transitions to specific energy levels in hydrogen. The Lyman Series (transitions to n=1) produces ultraviolet light, invisible to the human eye. The Balmer Series (transitions to n=2) produces visible light, which is crucial for astronomical observations. The Paschen Series (transitions to n=3) produces infrared light. Larger electron jumps produce higher-energy (shorter wavelength) photons, explaining the distinct ranges of these series.
Yes, flame tests directly demonstrate spectral fingerprints. When you heat a chemical like sodium chloride, its electrons become excited and emit light at specific wavelengths, producing a characteristic bright yellow flame. Similarly, fireworks use different elements to create specific colors: copper compounds produce blue, sodium produces yellow, and calcium produces orange. These are real-world applications of the same atomic processes used to analyze stars.
A star's temperature determines which spectral lines are most prominent. Hotter stars have more high-energy ultraviolet lines from the Lyman series, while cooler stars show more visible and infrared lines. The intensity and width of the absorption lines also vary with temperature, as it affects the number of atoms in different excitation states. By analyzing the spectral pattern and line strengths, astronomers can estimate a star's temperature and even its composition.
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