Understanding Oxyacids: Formation, Naming, and Formulas Explained

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What Are Oxyacids?

Oxyacids are acids formed from hydrogen and polyatomic oxyanions. For example:

  • Nitric acid (HNO3) forms from the nitrate ion (NO3−)
  • Sulfuric acid (H2SO4) forms from the sulfate ion (SO42−)
  • Sulfurous acid (H2SO3) forms from the sulfite ion (SO32−)

Dissociation of Oxyacids in Water

When oxyacids dissolve in water, they dissociate into hydrogen ions (H+) and the corresponding polyatomic ion:

  • HNO3 → H+ + NO3−
  • H2SO4 → 2H+ + SO42−

Note that the polyatomic ion remains intact; nitrogen and oxygen atoms do not separate individually. The number of hydrogen ions released corresponds to the charge on the polyatomic ion (e.g., sulfate has a charge of -2, so two H+ ions are released).

Naming Patterns of Oxyacids

The naming of oxyacids depends on the suffix of the oxyanion:

  • Oxyanions ending with -ite form acids ending with -ous (e.g., nitrite → nitrous acid, sulfite → sulfurous acid)
  • Oxyanions ending with -ate form acids ending with -ic (e.g., nitrate → nitric acid, sulfate → sulfuric acid)

Examples:

| Oxyanion | Charge | Acid Name | Acid Formula | |----------|---------|-----------------|--------------| | Nitrite | -1 | Nitrous acid | HNO2 | | Nitrate | -1 | Nitric acid | HNO3 | | Sulfite | -2 | Sulfurous acid | H2SO3 | | Sulfate | -2 | Sulfuric acid | H2SO4 | | Chlorite | -1 | Chlorous acid | HClO2 | | Chlorate | -1 | Chloric acid | HClO3 |

Writing the Formula of Sulfuric Acid

To write the formula for sulfuric acid:

  1. Identify the cation: hydrogen (H+)
  2. Identify the anion: sulfate (SO42−)
  3. Balance charges: two H+ ions balance one SO42− ion
  4. Write the formula: H2SO4
  5. Indicate aqueous state: H2SO4 (aq)

This method ensures the total positive and negative charges cancel out.

Additional Notes

  • Binary acids (e.g., hydrochloric acid) contain only two elements and start with "hydro" and end with "-ic acid".
  • Understanding the relationship between oxyanion suffixes and acid names simplifies memorization.
  • Common polyatomic ions and their corresponding acids include acetate → acetic acid and carbonate → carbonic acid.

By recognizing these patterns and practicing formula writing, naming oxyacids becomes straightforward and intuitive.

For a deeper understanding of the underlying concepts, you may find the following resources helpful:

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